Definitely, Klaus. He went from a drug addict to becoming nearly sober to find his partner Dave, and was able to (nearly) bring back Ben to the point he was able to physically punch Klaus.
And of course season 2, again he became completely sober and explored his powers more. Along with Vanya, since she learned to control her powers. Personally, I feel like Klaus was really developed within the two seasons, with Vanya coming in second and Luther third.